Assessment of mercury mobility and bioavailability by fractionation method in sediments from coastal zone inundated by the 26 December 2004 tsunami in Thailand     

Leonard Boszke  Artur Kowalski  Witold Szczuciński  Grzegorz Rachlewicz  Stanisław Lorenc  Jerzy Siepak 《Environmental Geology》2006,51(4):527-536

The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g⁻¹ dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them.  相似文献   

Glacial Erosion in the Abisko Mountains: Kärkevagge and Vassivagge, Northern Sweden     

Jerzy Mo&#;cicki  Adam Kotarba  Stanis&#;aw K&#;dzia 《Geografiska Annaler: Series A, Physical Geography》2006,88(2):151-163

This paper discusses direct current resistivity soundings and geomorphological studies of Quaternary deposits in two glacial troughs in the Abisko Mountains of northern Sweden. The subject of the fieldwork is the depth of Pleistocene glacial erosion. Studies were carried out in 1998 and 2003 in the Kärkevagge and Vassivagge. The estimated thickness of Quaternary deposits and bedrock properties are discussed in the broader context of glacial erosion studies in the Abisko area. Geophysical and geomorphological studies suggest that the depth of glacial erosion was highly differentiated from –190 m in the Torneträsk basin to the metric overall erosion on the upland plateau. In medium‐sized valleys several kilometres long, erosion depth measures 30–50 m. Present‐day stream channel patterns reveal a strong relation to the bedrock configuration in valley floors  相似文献   

Redbed-type gold mineralisation, Kupferschiefer, south-west Poland     

Adam Piestrzyński  Jadwiga Pieczonka  Adam Głuszek 《Mineralium Deposita》2002,37(5):512-528

A new type of gold mineralisation containing minor amounts of platinum and palladium has been found proximal to the secondary redox interface located below the Cu-Ag Kupferschiefer orebody of the Polkowice-Sieroszowice mine in the south-western part of the Lubin-Sieroszowice district, Poland. This deposit can be classified as redbed-type gold. Our study shows that gold, platinum and palladium occur in secondary red-coloured sections of the basal Zechstein sedimentary rocks and in the uppermost Weissliegendes sandstone. Noble metal mineralisation occurs within an average interval of 0.22 m, which lies directly below the copper ores. The average grade of the horizon is 2.25 ppm Au, 0.138 ppm Pt and 0.082 ppm Pd with a metal content of several tens of tonnes of gold. A transition zone has been recognised between the gold-bearing horizon and the copper deposit. This transition zone is characterised by the presence of low grades of copper (<0.2 wt%) and elevated gold contents (>0.5 ppm). Native gold accompanied by electrum, mercury-bearing gold, haematite, covellite, chalcocite, bornite and chalcopyrite has been identified in the gold-bearing horizon. In some sections, Pd-arsenides, tetra-auricupride, Co-arsenides, clausthalite, tennantite, digenite, yarrowite, spionkopite and galena have also been noted.  相似文献   

Finite-difference modelling of two-dimensional elastic wave propagation in cracked media     

Vincent A. van Antwerpen  Wim A. Mulder  Gérard C. Herman 《Geophysical Journal International》2002,149(1):169-178

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Brunet, Roger; Eckert, Denis; Kolossov, Vladimir: Atlas de la Russie et des pays proches.     

Herman van der Wusten 《GeoJournal》1997,42(4):467-467

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Beyond Route 66: Some observations on US geography at AAG 100     

Herman van der Wusten 《GeoJournal》2004,59(1):47-50

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Macrocrystal phlogopite Rb–Sr dates for the Ekati property kimberlites, Slave Province, Canada: evidence for multiple intrusive episodes in the Paleocene and Eocene     

Robert A. Creaser  Herman Grütter  Jon Carlson  Barbara Crawford   《Lithos》2004,76(1-4):399-414

New Rb–Sr age determinations using macrocrystal phlogopite are presented for 27 kimberlites from the Ekati property of the Lac de Gras region, Slave Province, Canada. These new data show that kimberlite magmatism at Ekati ranges in age from at least Late Paleocene (61 Ma) to Middle Eocene time (45 Ma). Older, perovskite-bearing kimberlites from Ekati extend this age range to Late Cretaceous time (74 Ma). Within this age range, emplacement episodes at 48, 51–53, 55–56 and 59–61 Ma can be recognized. Middle Eocene kimberlite magmatism of the previously dated Mark kimberlite (47.5 Ma) is shown to include four other pipes from the east-central Ekati property. A single kimberlite (Aaron) may be younger than the 47.5 Ma Mark kimberlite. The economically important Panda kimberlite is precisely dated in this study to be 53.3±0.6 Ma using the phlogopite isochron method, and up to six additional kimberlites from the central Ekati property have Early Eocene ages indistinguishable from that of Panda, including the Koala and Koala North occurrences. Late Paleocene 55–56 Ma kimberlite magmatism, represented by the Diavik kimberlite pipes adjacent to the southeastern Ekati property, is shown to extend onto the southeastern Ekati property and includes three, and possibly four, kimberlites. A precise eight-point phlogopite isochron for the Cobra South kimberlite yields an emplacement age of 59.7±0.4 Ma; eight other kimberlites from across the Ekati property have similar Late Paleocene Rb–Sr model ages. The addition of 27 new emplacement ages for kimberlites from the Ekati property confirms that kimberlite magmatism from the central Slave Province is geologically young, despite ages ranging back to Cambrian time from elsewhere in the Slave Province. With the available geochronologic database, Lac de Gras kimberlites with the highest diamond potential are currently restricted to the 51–53 and 55–56 Ma periods of kimberlite magmatism.  相似文献   

Deciphering late Devonian–early Carboniferous P–T–t path of mylonitized garnet-mica schists from Prins Karls Forland,Svalbard     

Karolina Kośmińska  Frank S. Spear  Jarosław Majka  Karol Faehnrich  Maciej Manecki  Karsten Piepjohn  Winfried K. Dallmann 《Journal of Metamorphic Geology》2020,38(5):471-493

Quartz-in-garnet inclusion barometry integrated with trace element thermometry and calculated phase relations is applied to mylonitized schists of the Pinkie unit cropping out on the island of Prins Karls Forland, western part of the Svalbard Archipelago. This approach combines conventional and novel techniques and allows deciphering of the pressure–temperature (P–T) evolution of mylonitic rocks, for which the P–T conditions could not have been easily deciphered using traditional methods. The results obtained suggest that rocks of the Pinkie unit were metamorphosed under amphibolite facies conditions at 8–10 kbar and 560–630°C and mylonitized at ~500 to 550°C and 9–11 kbar. The P–T results are coupled with in-situ Th–U-total Pb monazite dating, which records amphibolite facies metamorphism at c. 359–355 Ma. This is the very first evidence of late Devonian–early Carboniferous metamorphism in Svalbard and it implies that the Ellesmerian Orogeny on Svalbard was associated with metamorphism up to amphibolite facies conditions. Thus, it can be concluded that the Ellesmerian collision between the Franklinian margin of Laurentia and Pearya and Svalbard caused not only commonly accepted brittle deformation and weak greenschist facies metamorphism, but also a burial and deformation of rock complexes at much greater depths at elevated temperatures.  相似文献   

A reconstruction of the palaeohydrological conditions of a flood‐plain: a multi‐proxy study from the Grabia River valley mire,central Poland          下载免费PDF全文

Dominik Pawłowski  Grzegorz Kowalewski  Krystyna Milecka  Mateusz Płóciennik  Michał Woszczyk  Tomasz Zieliński  Daniel Okupny  Wojciech Włodarski  Jacek Forysiak 《Boreas: An International Journal of Quaternary Research》2015,44(3):543-562

This study investigated the Grabia River valley mire in central Poland to reconstruct its palaeoenvironmental conditions from the Younger Dryas to the present. We analysed sedimentological, biological and geochemical data from the palaeo‐oxbow lake and valley mire to identify the principal hydrological trends, especially episodes of high water level. During the Lateglacial and Holocene, the Grabia River had a meandering channel, and its hydraulic parameters and the channel dimensions changed in response to climatic oscillations and vegetation development. We identified phases of high flood intensity and high groundwater level that correlate with regional and supraregional climatic events. The frequency and timing of palaeohydroclimatic oscillations show strong similarities to records from other sites in Poland and the rest of Europe. We show that various analytical methods, namely, pollen, plant macrofossils, Cladocera, Chironomidae, sedimentological, geochemical and radiocarbon data, can be effective tools for reconstructing past hydroclimatic changes in palaeo‐oxbow lakes and investigating the effects of past climate changes on river environments. The high sensitivity of the biota, especially Cladocera, to changes in water level permits the reconstruction of palaeoecological changes, especially flood episodes that occurred in the river valley. In particular, the increase in the proportion of sediment‐associated Cladocera and pelagic taxa was closely correlated with floods. Through comparisons with the palaeobiological data, geochemical data allowed the identification of humid phases within the fen associated with a rising groundwater table, direct fluvial activity (floods) and alluvial deposition. We also discuss the limitations of palaeohydrological reconstructions based on these proxies, especially on fossil aquatic invertebrates.  相似文献   

Intensity of in‐lake processes in floodplain lakes within the Bug River zone of fluvial activity          下载免费PDF全文

Jarosław Dawidek  Beata Ferencz 《水文研究》2014,28(24):5965-5971

The paper presents a new approach to calculating the erosion and deposition values of floodplain lake basins, the erosion–deposition index (EDI). The EDI is a sum of the basin geometry indices (BGIs), which can be calculated for a separate cross section of the lake. The distribution of processes within the basin was investigated in two selected floodplain lakes with the use of BGIs. Field research was carried out in the Bug River valley from 1 November 2006 to 31 October 2011. The highest erosion was observed in the lakes located close to the parent river. Deposition processes were observed in lakes with high inflow of groundwater. The results showed that EDI values of 48 out of the 71 floodplain lakes ranged from ?0.2 to 0.2. Spatial distribution of erosion and deposition processes within the lake basins resulted from a velocity of water inflowing or flowing through the basin. This was observed especially in contrafluent–confluent lake. Inflow of rivers water via upstream crevasse occurred later than via downstream one, but energy of flowing water was higher, which favoured erosion of this part of the lake basin. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献